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For four of these metabolites (homotaurine, N -acetyl-phenylalanylleucine/isoleucine, 3-hydroxypropane-1-sulfonic acid, and N 1 -methyl-imidazolelactic acid), the chemical standard did not match to the original tissue peak, but instead matched a peak with a distinct MS/MS spectrum and/or a retention time difference that could not be explained by chromatographic drift (see also Success rate of metabolite discovery)

Toker L, Amar S, Bersudsky Y, Benjamin J, Klein E (2010) The biology of tryptophan depletion and mood disorders

The KIT gene controls mast cell creation from stem cells in the bone marrow, and mutations in KIT cause excess mast cell proliferation.[ref][ref] A mastocytosis diagnosis is either systemic mastocytosis (affecting the whole body) or cutaneous mastocytosis, which has more skin-related symptoms

At higher concentrations, MMP2 and MMP9 decrease, preventing excessive collagen degradation