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Kawano H, Otani M, Takeyama K, Kawai Y, Mayumi T, and Hama T

The measured band at 1620 cm 1 arises from coupled C2=N3 and C5=C6 stretches, whereas the measured band at 1570 cm 1 results from C4C5 stretching coupled to O4H bending

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& Colman, D

The reason for occurring this phenomenon (reduction of CySGly- but not of GS-bound Mercury(II)) in solution and in the biological environment of cells is reasonably a consequence of the low reducing electrochemical potential of CySGly (at 0.282 V the most reducing one of the whole soluble physiological thiolome)

Bioavailability is the measure of how much of a substance actually enters your bloodstream and reaches the cells that need it