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Chloroacetamide electrophiles are relatively reactive toward nucleophilic residues

doi: 10.1128/mBio.01017-13

This promising peptide is renowned for boosting the activity of brain-derived neurotrophic factor (BDNF), an integral protein in the brain that is responsible for promoting neuron growth, differentiation, and overall synaptic plasticity

in DEM treated cells the growth is delayed until the higher level of nuclear GSH is reached, which occurs at 4872 h, while in the BSO treated cells the maintained high level of nuclear GSH between 48 h72 h results in a prolonged cell growth when compared to control

It is possible that the utilization of glutamate in these various processes is adaptation of ancient non-enzymatic processes that relied on the unique capability of glutamate and aspartate to form cyclic anhydrides