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112 More recently, it was suggested that methotrexate causes ferroptosis through activation of autophagy, leading to increased degradation of ferritin and liberation of ferrous iron (ferritinophagy), which promotes LPO and liver injury

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Metformins effects also extend to cardiovascular risk reduction as it influences key metabolic pathways to improve lipid metabolism and endothelial function, potentially lowering the risk of cardiovascular events (Lan et al., 2015)

Redox chemistry of reduced pterin species