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Rizzo et al., 2017)

Once oxidised, the compound cannot be restored

The free fraction is responsible for the actions in the target tissues, which include virtually all cells

This form is known as sodium R-lipoate, or Na-RALA

Thus, changes in the GSH/GSSG ratio are fundamental in the fine-tuning of signal transduction, even under mild oxidative stress that underlies physiological events such as cell cycle regulation and other cellular processes (Schafer and Buettner, 2001)

In sequence terms, that Cterminal block is exactly the kind of motif that enables membrane penetration, The region: ArgArgSerGlyGlyLysArgProProProArgArgArgGlnArgArgLysLysArgGlyOH` has all the hallmarks of a CPP: High local positive charge density Arginine is the key driver the guanidinium group forms bidentate hydrogen bonds with phosphate and sulfate groups on the cell surface (heparan sulfate proteoglycans, phospholipid headgroups)