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Description
In the key step, this intermediate is reduced by catalytic hydrogenation with a transfer of chirality to the carbon atom alpha to the amino group
There is evidence that the synthesis of very-long-chain C24 sphingolipids, mediated by ceramidase isoform 2, is regulated by the availability of long-chain fatty acids, mediated by fatty acid elongase 1 (Reference Ohno, Suto and Yamanaka52)
[DOI] [PubMed] [Google Scholar] 91.Stumpf DA, McAfee J, Parks JK, Eguren L
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10.1021/cr9402034 174 KawalleckP.KellerH.HahlbrockK.ScheelD.SomssichI
