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Larger proteins can be more freeze-thaw sensitive than short peptides, not less so if anything these are conservative comparisons

It may be that your body isnt absorbing, or your demands are higher than you can keep up with just using diet and supplements

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DAMPs and DAMP-sensing receptors in inflammation and diseases

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Conclusion This RCT provides evidence to show that GlyNAC supplementation in OA improves GSH deficiency, OxS, mitochondrial impairment, mitophagy, inflammation, insulin resistance, endothelial dysfunction, physical function and strength, exercise capacity, waist circumference, state systolic blood pressure, and multiple hallmarks of aging (mitochondrial dysfunction, altered intercellular communication, dysregulated nutrient sensing, loss of proteostasis, genomic toxicity, stem-cell exhaustion, and cellular senescence)