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Tissue-based map of the human proteome

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Fitch III WP, Easterling WJ, Talbert RL, Bordovsky MJ, Mosier M

[13] In the first step of the reaction, acyl-CoA synthetase catalyzes the transfer of adenosine monophosphate group (AMP) from an ATP molecule onto the fatty acid generating a fatty acyladenylate intermediate and a pyrophosphate group (PP i )

Thus further work needs to be done to clarify this issue

But no matter where it comes from, if you ingest too much caffeine, your body cant process it fast enough and you may have an overdose