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If it breaks down, things can leak through

Transcriptional induction of genes encoding endoplasmic reticulum resident proteins requires a transmembrane protein kinase

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When compounds 1a and d 8 - 1a were used as substrates under S-mediated reaction conditions, the HRMS data showed that the para amide transfer via an intramolecular pathway and the mixed acetamide migration products were not detected

doi: 10.1016/S1499-3872(17)60041-9

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