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When lipoic acid is free rather than enzyme-bound, it can cycle between its two forms the closed-ring oxidised form and the open-ring reduced form, dihydrolipoic acid, with its two free thiols

Moreira et al., 2007

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doi: 10.4103/0972-6691.116608 Jain, S., Parsanathan, R., Achari, A., Kanikarla-Marie, P., & Bocchini, J