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Int J Mol Sci 2013, 14:47054721

Amano H, Uchida H, Harada K, Narita A, Fumino S, Yamada Y, Kumano S, Abe M, Ishigaki T, Sakairi M, Shirota C, Tainaka T, Sumida W, Yokota K, Makita S, Karakawa S, Mitani Y, Matsumoto S, Tomioka Y, Muramatsu H, Nishio N, Osawa T, Taguri M, Koh K, Tajiri T, Kato M, Matsumoto K, Takahashi Y, Hinoki A

doi: 10.1038/s41598-020-67033-2

TCM enhances the immune system and TME immune signaling pathways, showing promise as an adjuvant to ICIs, particularly in CRC.Unlike conventional therapies focusing on direct tumor cell cytotoxicity, TCM leverages TME immune signaling modulation to stimulate immune responses, suppress tumor progression, and improve immunity (95, 96)

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The biological sample of any one of embodiments 24 to 26, wherein the maleimide-alkylated GSH and/or the heavy isotopologue thereof is present in the sample at a concentration of at least 0.0001 ppm, preferably at least 0.001 ppm, more preferably at least 0.01 ppm, even more preferably at least 0.1 ppm, in particular at least 1 ppm or even at least 10 ppm