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In this case, the Ile31 peptide carbonyl oxygen, being within a van der Waals distance from the S-atom of Met35 (121), coupled to the greater electronegativity of oxygen compared to sulfur, the lone-pair electrons around the S-atom of Met35 would be drawn toward the Ile31 oxygen and away from the attraction of the protons in the S-nucleus in Met35

1960-

Ca 2+ is not metabolized and an overload of mitochondrial Ca 2+ may break down the electrochemical proton gradient resulting in a deficit of ATP followed by necrosis [89]