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One reason behind this is that cigarettes produce nicotine, which is a chemical known for causing temporary feelings of relaxation whenever it enters ones bloodstream

Soc Sci Med 2006, 63: 1034-1044

The smoking ban also includes electronic cigarettes, which can still pose a fire risk due to their batteries, and also expose others to secondhand smoke or unregulated chemicals

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Animal studies indicate that pure nicotine is only weakly addictive but data on human drug use indicate that the addictive potential of tobacco is very high