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Nicotine and its primary metabolite, cotinine, are well-known to interfere with the normal functioning of the endocrine system by triggering the release of catecholamines such as adrenaline

BusinessWeek (30 October 2005)

The exact mechanism of why nicotine withdrawal causes headaches still isnt known, but it may have to do with nicotines effect on pain processing in your brain

Psychological addiction is far more insidious than physical addiction

[8] Some areas have found that Tobacco 21 policies can be developed and adopted in a shorter time frame and with fewer resources, can be targeted to a smaller group of stakeholders, and are perceived as less politically risky than other tobacco control measures such as smoke-free policies