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Incorporating this constant into the equilibrium expression allows us to rearrange Equation 16.5 to define a new equilibrium constant, the ion-product constant of liquid water ( K w )An equilibrium constant for the autoionization of water, + in which the concentration of water is treated as a constant: = = : Equation 16.7 Substituting the values for [H 3 O + ] and [OH ] at 25C into this expression, Equation 16.8 Thus, to three significant figures, K w = 1.01 10 14 M